UN1744 溴或溴溶液

深暗棕色带有强刺激性气味的 重质液体。密度：3.1(纯品)。 沸点：59℃。强氧化剂；与有 机物如木、棉花或草接触会着 火。对大多数金属有强烈腐蚀 性。依据其浓度不同，溶液与 较小浓度溶液具有相同的特 性。吞咽、与皮肤接触或吸入 会中毒。灼伤皮肤、眼睛和黏 膜。

Very dark brown, heavy liquid with an extremely irritating odour. Density: 3.1 (pure product). Boiling point: 59 C. Powerful oxidant; ° may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Solutions have the same properties to a lesser degree, depending on concentration. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes.

出处：IMDG Code 42-24 第 649 页

P804

P804 本导则适用于UN 1744。 只要符合第4.1.1和4.1.3节的规定，且包装为密封，允许使用下列包装： （1） 组合包装，最大毛重为 25kg，由一个或多个玻璃内容器组成，每个内容器的最大容量为 1.3L，且装载量不超过其容量的 90%；其封盖须以任何能够防止运输过程中撞击或振动而脱落或松动的方式固定，单独放置在： （a）金属或硬质塑料容器内，连同足以吸收玻璃内容器全部内装物的衬垫和吸收材料，进一步包装在； （b）1A1、1A2、1B1、1B2、1N1、1N2、1H1、1H2、1D、1G、4A、4B、4N、 4C1、4C2、4D、4F、4G或4H2外包装中。 （2） 组合包装由金属或聚偏氟乙烯 （PVDF）内包装组成，单个内包装容量不超过 5L，内衬足以吸收内装物的吸附材料和惰性衬垫材料，外包装为 1A1、1A2、1B1、1B2、 P804 1N1、1N2、1H1、1H2、1D、1G、4A、4B、4N、4C1、4C2、4D、4F、4G 或 4H2，最大总质量为 75kg。内包装的装载量不得超过其容量的 90%。每个内包装的封口均须以任何能够防止在运输过程中因撞击或振动而脱落开或松动的方式固定到位。 （3） 包装的组成： 外包装： 钢或塑料桶（1A1、1A2、1H1或 1H2）按照第 6.1.5节要求进行试验，试验质量相当于集合包装的质量，既可以作为用于容纳内包装的包装，也可以作为用于容纳固体或液体的单一包装，并进行相应标记； 内包装： 桶和复合包装（1A1、1B1、1N1、1H1 或 6HA1）符合第 6.1 章关于单一包装的要求，但须符合以下条件： （a）液压试验须采用至少为300kPa（3巴）（表压）的压力进行； （b）设计和产品泄漏试验须采用至少30kPa（0.3巴）的压力进行； （c） 内包装须使用惰性减振衬垫材料包围在内包装各侧使其与外桶隔离； （d）内包装容量须不超过125L； （e）封盖须为螺旋型，且： （i） 采用任何能够防止在运输过程中因撞击或振动而导致封盖脱落或松动的装置将其物理固定； （ii） 配有封盖； （f） 外包装和内包装须定期进行内部检查并根据（b）段要求每两年半进行泄漏试验；以及 （g） 外包装和内包装须以清晰、易读、耐久的字符标明： （i） 初始试验和最近的定期试验及内包装检查的日期（月、年）；以及 （ii） 进行试验和检查的专家的姓名或授权符号。 （4） 符合第4.1.3.6条一般规定的压力容器： （a）压力容器须每 10 年接受一次初始试验和定期试验，试验压力不得低于 1 MPa （10 bar）（表压）； （b）须定期进行内部检查并以不超过两年半间隔进行泄漏试验； （c）不得配备任何压力释放装置； （d）压力容器须使用配备有二次关闭装置的塞子或阀门关闭；以及 （e）压力容器、阀门、塞子、出口盖、密封胶和垫片的制造材料须相互兼容并与内装物相容。

P804 This instruction applies to UN 1744. The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 25 kg, consisting of one or more glass inner packaging(s) with a maximum capacity of 1.3 L each and filled to no more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during transport, individually placed in: (a) metal or rigid plastics receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in: (b) 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings. (2) Combination packagings consisting of metal or polyvinylidene fluoride (PVDF) inner packagings, not exceeding L in capacity individually packed with absorbent material sufficient to absorb the contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport. (3) Packagings consisting of: Outer packagings: Steel or plastics drums (1A1, 1A2, 1H1 or 1H2) tested in accordance with the test requirements in 6.1.5 at a mass corresponding to the mass of the assembled package either as a packaging intended to contain inner packagings, or as a single packaging intended to contain solids or liquids, and marked accordingly; Inner packagings: Drums and composite packagings (1A1, 1B1, 1N1, 1H1 or 6HA1) meeting the requirements of chapter 6.1 for single packagings, subject to the following conditions: (a) The hydraulic pressure test shall be conducted at a pressure of at least 300 kPa (3 bar) (gauge pressure); (b) The design and production leakproofness tests shall be conducted at a test pressure of 30 kPa (0.3 bar); (c) They shall be isolated from the outer drum by the use of inert shock-mitigating cushioning material which surrounds the inner packaging on all sides; (d) Their capacity shall not exceed 125 L; (e) Closures shall be of a screw type that are: (i) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport; (ii) Provided with a cap seal; (f) The outer and inner packagings shall be subjected periodically to an internal inspection and leakproofness test according to (b) at intervals of not more than two and a half years; and (g) The outer and inner packagings shall bear in clearly legible and durable characters: (i) the date (month, year) of the initial test and the latest periodic test and inspection of the inner packaging; and (ii) the name or authorized symbol of the expert performing the tests and inspections. (4) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. (a) They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than MPa (10 bar) (gauge pressure); (b) They shall be subjected periodically to an internal inspection and leakproofness test at intervals of not more than two and a half years; (c) They may not be equipped with any pressure relief device; (d) Each pressure receptacle shall be closed with a plug or valve(s) fitted with a secondary closure device; and (e) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the contents.

出处：IMDG Code 42-24 第 225 页（4.1.4.1）

T22

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质，须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外，第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 （单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢） （见第6.7.2.8 （见第6.7.2.6 （bar） （见第6.7.2.4 条） 条） 条） 10 10mm 见6.7.2.8.3 不允许 a 当标明“正常”时，除第6.7.2.8.3条外，第6.7.2.8条的所有规定均适用。 b 当此栏标明“不允许”时，当运输的物质为液体时，不允许底部开口（见第6.7.2.6.1条）。 当运输的物质在正常运输条件下遇到的所有温度下均为固体时，允许符合第6.7.2.6.2条规定的底部开口。

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 10 10 mm See 6.7.2.8.3 Not allowed a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

不得超过第4.2.1.9.3条中规定的充灌度。

The degree of filling prescribed in 4.2.1.9.3 shall not be exceeded.

要求使用不少于5mm厚的铅衬里，该衬里须每年进行一次测试，或需经主管当局批准的其他合适的衬里材料。可移动罐柜可在上一次衬里检查到期后运输，运输时间不得超过该日期后的三个月，在卸空后但清洗前，以便在重新装载之前进行下一次所需的试验或检查。

A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority is required. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months beyond that date, after emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling.

运输该物质时须配备自给式呼吸器，除非船上未配备《安全公约》第 II- 2/19（II-2/54）条所要求的的自给式呼吸器。

Self-contained breathing apparatus shall be provided when this substance is transported, unless no self-contained breathing apparatus, as required by SOLAS regulation II-2/19 (II-2/54), is on board.

避开热源。

Protected from sources of heat.

避开生活居住处所。

Clear of living quarters.

1 酸类

1 acids

按第5.1类隔离。

Segregation as for class 5.1.

与第4.1类“隔离”。

Stow “separated from” class 4.1.

与第5.1类“隔离”。

Stow “separated from” class 5.1.

与第7类“隔离”。

Stow “separated from” class 7.

与SGG18 - 碱类“隔离”。

Stow “separated from” SGG18 – alkalis.

与SGG8 - 氰化物“隔离”。

Stow “separated from” SGG6 – cyanides.