IMDG Code 42-24 · Dangerous Goods List

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UN1744BROMINE or BROMINE SOLUTION

English proper shipping name · Check the cargo and applicable provisions before shipment.

Class8
Packing groupI
EmSF-A, S-B

Dangerous Goods List entries

The comparison below lists all entries. Expanded provisions and the label preview on this page apply to Entry 1.

Compare all 1 DGL entry

Entry 1 · Packing group I

BROMINE or BROMINE SOLUTION

Class
8
Subsidiary risk / reference
6.1
Packing group
I
Marine pollutant entry
Not listed; check the cargo classification
Limited quantities
0
Excepted quantities
E0
Packing instruction
P804
Special provisions
Not listed
Special packing provision
Not listed
IBC instruction
Not listed
IBC special provisions
Not listed
Portable tank / bulk container codes
T22
Tank special provisions
TP2 TP10 TP13
EmS
F-A, S-B
Stowage and handling
Category D SW1 SW2 H2 Category D SW1 SW2 H2
Segregation
SGG1 SG6 SG16 SG17 SG19 SG36 SG49
Properties and observations · source text
Very dark brown, heavy liquid with an extremely irritating odour. Density: 3.1 (pure product). Boiling point: 59 C. Powerful oxidant; ° may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Solutions have the same properties to a lesser degree, depending on concentration. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes.

Packing and large packaging instructions

P804

Source pages and references

Check original English pages and footnotes ↗ · official PDF 221–221

P804 This instruction applies to UN 1744. The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 25 kg, consisting of one or more glass inner packaging(s) with a maximum capacity of 1.3 L each and filled to no more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during transport, individually placed in: (a) metal or rigid plastics receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in: (b) 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings. (2) Combination packagings consisting of metal or polyvinylidene fluoride (PVDF) inner packagings, not exceeding L in capacity individually packed with absorbent material sufficient to absorb the contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport. (3) Packagings consisting of: Outer packagings: Steel or plastics drums (1A1, 1A2, 1H1 or 1H2) tested in accordance with the test requirements in 6.1.5 at a mass corresponding to the mass of the assembled package either as a packaging intended to contain inner packagings, or as a single packaging intended to contain solids or liquids, and marked accordingly; Inner packagings: Drums and composite packagings (1A1, 1B1, 1N1, 1H1 or 6HA1) meeting the requirements of chapter 6.1 for single packagings, subject to the following conditions: (a) The hydraulic pressure test shall be conducted at a pressure of at least 300 kPa (3 bar) (gauge pressure); (b) The design and production leakproofness tests shall be conducted at a test pressure of 30 kPa (0.3 bar); (c) They shall be isolated from the outer drum by the use of inert shock-mitigating cushioning material which surrounds the inner packaging on all sides; (d) Their capacity shall not exceed 125 L; (e) Closures shall be of a screw type that are: (i) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport; (ii) Provided with a cap seal; (f) The outer and inner packagings shall be subjected periodically to an internal inspection and leakproofness test according to (b) at intervals of not more than two and a half years; and (g) The outer and inner packagings shall bear in clearly legible and durable characters: (i) the date (month, year) of the initial test and the latest periodic test and inspection of the inner packaging; and (ii) the name or authorized symbol of the expert performing the tests and inspections. (4) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. (a) They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than MPa (10 bar) (gauge pressure); (b) They shall be subjected periodically to an internal inspection and leakproofness test at intervals of not more than two and a half years; (c) They may not be equipped with any pressure relief device; (d) Each pressure receptacle shall be closed with a plug or valve(s) fitted with a secondary closure device; and (e) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the contents.

IMDG Code 42-24 · English source text

Portable tank instructions

T22

Source pages and references

Check original English pages and footnotes ↗ · official PDF 260–267

These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells.

T22 · Selected instruction · IMDG 42-24
Portable tank instructionMinimum test pressure (bar)Minimum shell thickness (in mm – reference steel) (see 6.7.2.4)Pressure relief provisionsa (see 6.7.2.8)Bottom opening provisionsb (see 6.7.2.6)
T221010 mmSee 6.7.2.8.3Not allowed

a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

Source PDF pages:264 · 42-24

Extracted source text
S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 10 10 mm See 6.7.2.8.3 Not allowed a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

IMDG Code 42-24 · English source text

Tank special provisions

TP10

Source pages and references

Check original English pages and footnotes ↗ · official PDF 268–268

A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority is required. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months beyond that date, after emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling.

IMDG Code 42-24 · English source text

TP13

Source pages and references

Check original English pages and footnotes ↗ · official PDF 268–268

Self-contained breathing apparatus shall be provided when this substance is transported, unless no self-contained breathing apparatus, as required by SOLAS regulation II-2/19 (II-2/54), is on board.

IMDG Code 42-24 · English source text

Stowage and handling codes

Handling provisions

Segregation groups

Segregation codes

Labels and marks

Reference preview for Entry 1 · Packing group I. Confirm the cargo classification and any conditions in the special provisions.

Corrosive 8
Corrosive 8
Toxic substance 6.1
Toxic substance 6.1

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