GALLIUM
| UN 编号 | UN2803 |
|---|---|
| 中文名称 | 镓 |
| 英文名称 | GALLIUM |
| 危险类别 | 第8类 |
| 包装类别 | III |
| 海洋污染物 | 否 |
| 有限数量 | 5 kg |
| 例外数量 | E0 |
| EmS 应急措施 | F-A,S-B(F-A, S-B) |
银白色金属元素,在29℃熔化 时成为明亮的液体。不溶解于 水。对铝有强腐蚀性。吞咽、 与皮肤接触或吸入有害。当使 用铝制货物集装箱载运时,如 发生渗漏,应特别小心。禁止 用气垫船及其铝质船运输。
Silvery-white metallic element that melts at 29 C, becoming a ° bright, shiny liquid. Insoluble in water. Highly corrosive to aluminium. Harmful if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs when carried in aluminium freight containers. Carriage should be prohibited in hovercraft and other ships constructed from aluminium.
出处:IMDG Code 42-24 第 704 页
本条目适用的包装导则: P800 ;有限数量 5 kg,例外数量 E0。
P800 本导则适用于UN 2803和2809。 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: (1) 符合第4.1.3.6条一般规定的压力容器。 (2) 容积不超过3.0L的带螺纹盖的钢桶或钢瓶;或 (3) 符合下列规定的组合包装: (a) 内容器须由玻璃、金属或硬质塑料制成,用于盛装液体,每个容器的最大净重为15kg。 (b) 内容器须使用足够的衬垫材料包装,以防止破裂。 (c) 内包装或外包装均须有内衬或袋,内衬或袋由坚固的防漏、防刺穿材料制成, 不渗透内装物,且完包裹住内装物,以防止其从包件中露出,不论其位置或方向如何。 (d) 允许使用下列外包装和最大净重: 外包装最大净重桶钢(1A1、1A2) 400kg 金属,不包括钢和铝(1N1、1N2) 400kg 塑料(1H1、1H2) 400kg 胶合板(1D) 400kg 纤维质(1G) 400kg 箱钢(4A) 400kg 金属,不包括钢和铝(4N) 400kg 天然木(4C1) 250kg 天然木,带防筛漏壁(4C2) 250kg 胶合板(4D) 250kg 再生木(4F) 125kg P800 纤维板(4G) 125kg 可发性塑料(4H1) 60kg 硬塑料(4H2) 125kg 特殊包装规定: PP41 对于 UN 2803,当需要在低温下运输镓以使其保持完全固态,上述包装可以装载坚固、防水的外包装中,外包装内装有干冰或其他制冷设备。当使用干冰或其他有窒息危险的制冷设备作为制冷剂时,须适用第 5.3.3 节的要求。如果适用制冷剂,则用于包装镓的所有上述材料均需在化学和物理上耐受制冷剂,并在所用制冷剂的低温下具有抗冲击性。如果使用干冰,外包装须允许释放CO 气体。须提供内部支撑以防止制冷剂消散后移动。
P800 This instruction applies to UN Nos. 2803 and 2809. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. (2) Steel flasks or bottles with threaded closures with a capacity not exceeding 3.0 L; or (3) Combination packagings which conform to the following provisions: (a) Inner packagings shall comprise glass, metal or rigid plastics intended to contain liquids with a maximum net mass of 15 kg each. (b) The inner packagings shall be packed with sufficient cushioning material to prevent breakage. (c) Either the inner packagings or the outer packagings shall have inner liners or bags of strong leakproof and puncture-resistant material impervious to the contents and completely surrounding the contents to prevent it from escaping from the package irrespective of its position or orientation. (d) The following outer packagings and maximum net masses are authorized: Outer packaging Maximum net mass Drums steel (1A1, 1A2) 400 kg metal, other than steel or aluminium (1N1, 1N2) 400 kg plastics (1H1, 1H2) 400 kg plywood (1D) 400 kg fibre (1G) 400 kg Boxes steel (4A) 400 kg metal, other than steel or aluminium (4N) 400 kg natural wood (4C1) 250 kg natural wood with sift-proof walls (4C2) 250 kg plywood (4D) 250 kg reconstituted wood (4F) 125 kg fibreboard (4G) 125 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 125 kg Special packing provision: PP41 For UN 2803, when it is necessary to transport gallium at low temperatures in order to maintain it in a completely solid state, the above packagings may be overpacked in a strong, water-resistant outer packaging which contains dry ice or other means of refrigeration. When dry ice or other means of refrigeration presenting a risk of asphyxiation are used as a coolant, the requirements of 5.5.3 shall apply. If a refrigerant is used, all of the above materials used in the packaging of gallium shall be chemically and physically resistant to the refrigerant and shall have impact resistance at the low temperatures of the refrigerant employed. If dry ice is used, the outer packaging shall permit the release of carbon dioxide gas. Interior supports shall be provided to prevent movement after the dissipation of the refrigerant.
出处:IMDG Code 42-24 第 223 页(4.1.4.1)
对于 UN 2803,当需要在低温下运输镓以使其保持完全固态,上述包装可以装载坚固、防水的外包装中,外包装内装有干冰或其他制冷设备。当使用干冰或其他有窒息危险的制冷设备作为制冷剂时,须适用第 5.3.3 节的要求。如果适用制冷剂,则用于包装镓的所有上述材料均需在化学和物理上耐受制冷剂,并在所用制冷剂的低温下具有抗冲击性。如果使用干冰,外包装须允许释放CO 气体。须提供内部支撑以防止制冷剂消散后移动。
For UN 2803, when it is necessary to transport gallium at low temperatures in order to maintain it in a completely solid state, the above packagings may be overpacked in a strong, water-resistant outer packaging which contains dry ice or other means of refrigeration. When dry ice or other means of refrigeration presenting a risk of asphyxiation are used as a coolant, the requirements of 5.5.3 shall apply. If a refrigerant is used, all of the above materials used in the packaging of gallium shall be chemically and physically resistant to the refrigerant and shall have impact resistance at the low temperatures of the refrigerant employed. If dry ice is used, the outer packaging shall permit the release of carbon dioxide gas. Interior supports shall be provided to prevent movement after the dissipation of the refrigerant.
本条目无中型散装容器(IBC)运输要求。
T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质,须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外,第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 (单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢) (见第6.7.2.8 (见第6.7.2.6 (bar) (见第6.7.2.4 条) 条) 条) 1.5 见6.7.2.4.2 正常见6.7.2.6.2
S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 1.5 See 6.7.2.4.2 Normal See 6.7.2.6.2
为该物质指定的可移动罐柜导则适用于粒状和粉末状固体以及在高于其熔点的温度下装填和排放并作为固体块冷却和运输的固体。对于在高于其熔点的温度下运输的固体,见第4.2.1.19条。
The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19.
本货物包件应张贴以下标签与标记:
8本 UN 可按有限数量运输(一览表额度 5kg);若本票按限量运输,须加贴 LQ 标记并符合第 3.4 章要求
本条目适用特殊规定: 365。
对于含有汞或镓的制成品和物品,请参见UN 3506 或 3554(视情而定)。
For manufactured instruments and articles containing mercury or gallium, see UN Nos. 3506 or 3554, as appropriate.
出处:IMDG Code 42-24 第 782 页
| 积载与操作 | 积载类B SW1(Category B SW1) |
|---|---|
| 隔离 | 一览表未列明隔离要求 |
避开热源。
Protected from sources of heat.
出口危险货物包装使用鉴定结果单(危包证)的办理逻辑,以及它和船级社证、钢瓶证、SOC 罐证分别在什么场景下用、向谁申请。
DG 申请表(DGD)被船公司退回,十有八九是这十个问题。逐条列出错误表现、船司退回话术和正确填法。
按 UN2803 自动带出类别、包装组、隔离要求与危包证清单,省掉翻书对表的时间。
生成 DG 申报资料 →