UN3090 锂金属电池（包括锂合金电池）

含有锂金属的电池可能会发生 反应（例如火焰、热量、释放 有毒、腐蚀性或易燃气体或蒸 汽）或因损坏、缺陷或短路而 解体。

Electrical batteries containing lithium metal may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit.

出处：IMDG Code 42-24 第 721 页

P903

P903 本导则适用于UN 3090、3091、3480、3481、3551和3552。 P903 就本包装规则而言，“设备”是指锂电池或锂电池组为其运行提供电力的设备。只要符合第 4.1.1和4.1.3节的一般规定，允许使用下列包装： （1） 电池和电池组： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2）。 包装在容器中的电池或电池组，须采取保护措施，防止电池或电池组免受在容器中移动或位置变化而可能造成的损坏。 容器须符合包装类II的性能指标。 （2） 此外，对于总重在 12kg 或以上的电池或电池组，如采用坚固、耐冲击的外壳，还须： （a） 坚固的外包装； （b） 保护性外罩（如全封闭或木板条箱）；或 （c） 托盘或其他搬运设备。 电池或电池组须紧固以防止意外移动，并且电极不得支撑其他叠加元件的重量。 包装无须符合第4.1.1.3条的要求。 （3） 对于与设备包装在一起的电池和电池组： 包装符合本包装规则第（1）款的要求，然后与设备一起放入外包装中；或包装完全包裹电池或电池组，然后与设备一起放入符合本包装规则第（1）款要求的包装中。 设备须固定以防止在外包装内移动。 在本包装规范中，“设备”是指需要与锂金属电池或电池组，或锂离子电池或电池组包装在一起供其运转的仪器。 （4） 对于装在设备中的电池或电池组： 外包装须使用足够坚固的材料制造，其强度和设计须与包装容量和预期用途相适应。包装须以能够防止运输过程中意外操作的方式制造。包装无需满足第4.1.1.3条的要求。 当电池或电池组受到其所在设备的同等保护时，大型设备可以无包装或放在托盘上运输。 当有意启动时，射频识别（RFID）标签、手表和温度记录器等不会产生危险热量的设备可以装在坚固的外包装中运输。 （5） 对于包含与设备一起包装和包含在设备中的电池或电池组的包装： （a） 对于电池和电池组，包装须完全包裹电池或电池组，然后与设备一起放符合本包装导则第（1）款要求的包装中；或 （b） 符合包装导则第（1）款要求的包装，与设备一起放入由合适材料制成的坚固外包装中，外包装的强度和设计须与包装容量和预期用途相适应。外包装的构造须能够防止运输过程中意外操作，且无需要满足第4.1.1.3条的要求。 P903 设备须固定以防止在外包装内移动。 有意启动的设备（如射频识别（RFID）标签、手表和温度记录器）不会产生危险的热量，因此可以使用坚固的外包装运输。 注：（2）、（4） 和 （5） 中允许的包装净重不得超过 400 kg（见第4.1.3.3条）。 补充规定： 电池或电池组须防止短路。

P903 This instruction applies to UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552. For the purpose of this packing instruction, “equipment” means apparatus for which the cells or batteries will provide electrical power for its operation. The following packagings are authorized provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) For cells and batteries: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Cells or batteries shall be packed in packagings so that the cells or batteries are protected against damage that may be caused by the movement or placement of the cells or batteries within the packaging. Packagings shall conform to the packing group II performance level. (2) In addition for a cell or a battery with a gross mass of 12 kg or more employing a strong, impact resistant outer casing: (a) Strong outer packagings; (b) Protective enclosures (e.g. fully enclosed or wooden slatted crates); or (c) Pallets or other handling devices. Cells or batteries shall be secured to prevent inadvertent movement, and the terminals shall not support the weight of other superimposed elements. Packagings need not meet the requirements of 4.1.1.3. (3) For cells or batteries packed with equipment: Packagings conforming to the requirements in paragraph (1) of this packing instruction, then placed with the equipment in an outer packaging; or Packagings that completely enclose the cells or batteries, then placed with equipment in a packaging conforming to the requirements in paragraph (1) of this packing instruction. The equipment shall be secured against movement within the outer packaging. (4) For cells or batteries contained in equipment: Strong outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use. They shall be constructed in such a manner as to prevent accidental operation during transport. Packagings need not meet the requirements of 4.1.1.3. Large equipment can be offered for transport unpackaged or on pallets when the cells or batteries are afforded equivalent protection by the equipment in which they are contained. When intentionally active, devices such as radio frequency identification (RFID) tags, watches and temperature loggers, which are not capable of generating a dangerous evolution of heat, may be transported in strong outer packagings. (5) For packaging containing both cells or batteries packed with equipment and contained in equipment: (a) F or cells and batteries, packagings that completely enclose the cells or batteries, then placed with equipment in a packaging conforming to the requirements in paragraph (1) of this packing instruction; or (b) P ackagings conforming to the requirements in paragraph (1) of this packing instruction, then placed with the equipment in a strong outer packaging constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use. The outer packaging shall be constructed in such a manner as to prevent accidental operation during transport and need not meet the requirements of 4.1.1.3. The equipment shall be secured against movement within the outer packaging. When intentionally active, devices such as radio frequency identification (RFID) tags, watches and temperature loggers, which are not capable of generating a dangerous evolution of heat, may be transported in strong outer packagings. Note: The packagings authorized in (2), (4) and (5) may exceed a net mass of 400 kg (see 4.1.3.3). Additional requirement: Cells or batteries shall be protected against short circuit.

出处：IMDG Code 42-24 第 227 页（4.1.4.1）

P908

P908 本导则适用于 UN3090、3091、3480、3481、3551 和 3552 下损坏或有缺陷的电池和电池组，包括装在设备中的电池和电池组。 只要符合第4.1.1和4.1.3节的一般规定，允许使用下列包装： 对于电池和电池组和含有电池和电池组的设备： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2）。 包装须符合包装类II的性能指标。 包装还须满足以下要求： （a）每个受损或有缺陷的电池或电池组或含有此类电池或电池组的设备均须单独包装于内包装中，并放置于外包装内。内包装或外包装须防漏，以防止电解液可能泄漏。 （b）每个内包装须被足够的不可燃和不导电的隔热材料包裹，以防止产生危险的热量。 （c） 适当时，密封包装须安装通风装置。 （d） 须采取适当措施，尽量减少振动和冲击的影响，防止包件内电池或电池组移动，从而可能导致运输过程中进一步损坏和危险情况。不可燃和不导电的衬垫材料以可用于满足此要求。 （e） 隔热材料和衬垫材料的不可燃性须根据包装设计国或制造国认可的标准进行评估。 P908 对于泄露的电池或电池组，须在内包装或外包装中添加足够的惰性吸收材料，以吸收任何泄露的电解液。 对于净重超过30kg的电池或电池组，每个外包装须限制为一个电池或电池组。 补充规定： 须防止电池或电池组短路。

P908 This instruction applies to damaged or defective cells and batteries, including those contained in equipment, of UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552. The following packagings are authorized provided the general provisions for 4.1.1 and 4.1.3 are met: For cells and batteries and equipment containing cells and batteries: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2) Jerricans (3A2, 3B2, 3H2) Packagings shall conform to the packing group II performance level. Packagings shall also meet the following requirements: (a) Each damaged or defective cell or battery or equipment containing such cells or batteries shall be individually packed in inner packaging and placed inside of an outer packaging. The inner packaging or outer packaging shall be leakproof to prevent the potential release of electrolyte. (b) Each inner packaging shall be surrounded by sufficient non-combustible and electrically non-conductive thermal insulation material to protect against a dangerous evolution of heat. (c) Sealed packagings shall be fitted with a venting device when appropriate. (d) Appropriate measures shall be taken to minimize the effects of vibrations and shocks, prevent movement of the cells or batteries within the package that may lead to further damage and a dangerous condition during transport. Cushioning material that is non-combustible and electrically non-conductive may also be used to meet this requirement. (e) The non-combustibility of the thermal insulation material and the cushioning material shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured. For leaking cells or batteries, sufficient inert absorbent material shall be added to the inner or outer packaging to absorb any release of electrolyte. A cell or battery with a net mass of more than 30 kg shall be limited to one cell or battery per outer packaging. Additional requirement: Cells or batteries shall be protected against short circuit.

出处：IMDG Code 42-24 第 230 页（4.1.4.1）

P909

P909 本包装导则适用于运输用于处置或回收的 UN 3090、3091、3480、3481、3551和3552的物品，这些物品可以与非锂电池组一起包装，也可单独包装。 （1） 电池和电池组须按下述要求包装： （a） 只要符合第4.1.1和4.1.3节的一般规定，允许使用下列包装： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H2）； 罐（3A2、3B2、3H2）。 （b） 包装须符合包装类II的性能指标。 （c） 金属包装须配有强度足以满足预期用途的非导电内衬材料（例如塑料）。 （2） 但是，瓦特-小时额定值不超过 20Wh 的锂离子或钠离子电池、瓦特-小时额定值不超过 100Wh 的锂离子或钠离子电池组、锂含量不超过 1g 的锂金属电池以及锂含量合计不超过2g的锂金属电池组可按下述要求包装： （a）装于符合第 4.1.1（第 4.1.1.3 条除外）和 4.1.3 节一般规定的坚固外包装内，总重不超过30kg。 （b）金属包装须配有强度足以满足预期用途的非导电内衬材料（例如塑料）。 （3） 对于装在设备中的电池或电池组，可使用由合适材料制成的坚固外包装，其强度和设计须与包装容量及预期用途相适应。包装无需满足第4.1.1.3条的要求。当电池或电池组由其所装设备提供同等保护时，设备也可在无包装或托盘上运输。 （4） 此外，对于总重12kg或以上的电池或电池组，如果采用坚固、耐冲击的外壳，可使用由合适材料制成的坚固外包装，其强度和设计须与包装容量及预期用途相适应。 包装无需满足第 4.1.1.3条的要求。 注：（3） 和 （4） 中允许的包装净重可超过 400 kg（见第 4.1.3.3条）。 补充规定： 电池和电池组的设计或包装须能防止短路和危险的发热。 防止短路和危险发热包括但不限于： （a） 电池两端的单独保护， （b） 内包装须防止电池和电池组之间接触， （c） 电池组设计成凹式终端以防短路，或 （d） 使用不导电且不易燃衬垫材料填充包装内电池和电池组之间的空隙。 P909 电池和电池组须固定在外包装内，以防止在运输中过度移动（例如使用不导电且不易燃的衬垫材料或使用密封的塑料袋）。

P909 This instruction applies to UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552 transported for disposal or recycling, either packed together with or packed without non-lithium batteries. (1) Cells and batteries shall be packed in accordance with the following: (a) The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3, are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2); and Jerricans (3A2, 3B2, 3H2). (b) Packagings shall conform to the packing group II performance level. (c) Metal packagings shall be fitted with an electrically non-conductive lining material (e.g. plastics) of adequate strength for the intended use. (2) However, lithium ion or sodium ion cells with a Watt-hour rating of not more than 20 Wh, lithium ion or sodium ion batteries with a Watt-hour rating of not more than 100 Wh, lithium metal cells with a lithium content of not more than 1 g and lithium metal batteries with an aggregate lithium content of not more than 2 g may be packed in accordance with the following: (a) In strong outer packaging up to 30 kg gross mass meeting the general provisions of 4.1.1, except 4.1.1.3, and 4.1.3. (b) Metal packagings shall be fitted with an electrically non-conductive lining material (e.g. plastics) of adequate strength for the intended use. (3) For cells or batteries contained in equipment, strong outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, may be used. Packagings need not meet the requirements of 4.1.1.3. Equipment may also be offered for transport unpackaged or on pallets when the cells or batteries are afforded equivalent protection by the equipment in which they are contained. (4) In addition, for cells or batteries with a gross mass of 12 kg or more employing a strong, impact resistant outer casing, strong outer packagings constructed of suitable material and of adequate strength and design in relation to the packagings capacity and its intended use, may be used. Packagings need not meet the requirements of 4.1.1.3. Note: The packagings authorized in (3) and (4) may exceed a net mass of 400 kg (see 4.1.3.3). Additional requirements: Cells and batteries shall be designed or packed to prevent short circuits and the dangerous evolution of heat. 2 Protection against short circuits and the dangerous evolution of heat includes, but is not limited to: (a) individual protection of the battery terminals, (b) inner packaging to prevent contact between cells and batteries, (c) batteries with recessed terminals designed to protect against short circuits, or (d) t he use of an electrically non-conductive and non-combustible cushioning material to fill empty space between the cells or batteries in the packaging. C ells and batteries shall be secured within the outer packaging to prevent excessive movement during transport (e.g. by using an electrically non-conductive and non-combustible cushioning material or through the use of a tightly closed plastics bag).

出处：IMDG Code 42-24 第 231 页（4.1.4.1）

P910

P910 本导则适用于 UN 3090、3091、3480、3481、3551和3552由不超过 100 个电池或电池组组成的生产批次，以及运输用于测试的预生产电池或电池原型。 只要符合第4.1.1和4.1.3节的一般规定，允许使用下列包装： (1) 对于电池和电池组，包括包装在设备中的电池和电池组： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2）。 包装须符合包装类II的性能指标，并满足下列要求： (a) 不同尺寸、形状或重量的电池和电池组，包括设备，只要包件总重不超过已测试的设计类型的总重量，须包装在经过上述测试的设计类型的外包装中； (b) 每个电池或电池组须独立包装后放入外包装内； (c) 每个内包装须完全被足够的不可燃和不导电的隔热材料包裹，以防止危险的热量释放； (d) 须采取适当措施，尽量减少振动和冲击的影响，并防止包装内的电池或电池组移动，从而可能导致在运输过程中的损坏和危险情况。可使用不可燃和不导电的衬垫材料来满足此要求； (e) 隔热材料金额衬垫材料的不可燃性须按照包装设计或制造国认可的标准进行评估； (f) 净重超过30kg的电池或电池组，每个外包装限装一个电池或电池组。 (2) 对于包含在设备中的电池或电池组： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2） 包装须符合包装类II的性能指标，并须满足下列要求： (a) 不同尺寸、形状、重量的设备须包装在经过测试的上述设计类型的外包装中，只要包件总重不超过设计已测试的设计类型的总重量； (b) 设备的构造或包装方式须防止运输途中的意外操作； (c) 须采取适当措施，尽量减少振动和冲击的影响，防止设备在包件内移动，从而导致运输过程中的损坏和危险情况。当使用衬垫材料来满足此要求时，该材料须不可燃且不导电；和 (d) 衬垫材料的不可燃性须按照包装设计或制造国认可的标准进行评估。 （3） 设备或电池组可在主管当局规定的条件下无包装运输。批准过程中可能考虑的其他条件但不限于： （a）设备或电池组须足够坚固，能够承受运输过程中通常遇到的冲击和负载，包括货 P910 物运输组件间、货物运输组件与仓库间、以及从托盘上移出以进行后续的人工或机械操作；和 （b）设备或电池组须固定在支架或板条箱或其他搬运装置内，以确保在正常运输条件下不会松动。 注：允许的包装净重可以超过 400kg（见第4.1.3.3条）。 补充规定： 电池或电池组须采取防短路措施。 防短路措施包括但不限于： （a） 电池两端独立保护； （b） 内包装可防止电池和电池组之间接触； （c） 电池组采取凹陷电极设计以防短路；或 （d） 使用不导电且不易燃的衬垫材料来填充包装内电池或电池之间的空隙。

P910 This instruction applies to UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552 production runs consisting of not more than 100 cells or batteries and to pre-production prototypes of cells or batteries when these prototypes are transported for testing. The following packagings are authorized provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) For cells and batteries, including when packed with equipment: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level and shall meet the following requirements: (a) Batteries and cells, including equipment, of different sizes, shapes or masses shall be packaged in an outer packaging of a tested design type listed above provided the total gross mass of the package does not exceed the gross mass for which the design type has been tested; (b) Each cell or battery shall be individually packed in an inner packaging and placed inside an outer packaging; (c) Each inner packaging shall be completely surrounded by sufficient non-combustible and electrically non-conductive thermal insulation material to protect against a dangerous evolution of heat; (d) Appropriate measures shall be taken to minimize the effects of vibration and shocks and prevent movement of the cells or batteries within the package that may lead to damage and a dangerous condition during transport. Cushioning material that is non-combustible and electrically non-conductive may be used to meet this requirement; (e) The non-combustibility of the thermal insulation material and the cushioning material shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured; (f) A cell or battery with a net mass of more than 30 kg shall be limited to one cell or battery per outer packaging. (2) For cells and batteries contained in equipment: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level and shall meet the following requirements: (a) Equipment of different sizes, shapes or masses shall be packaged in an outer packaging of a tested design type listed above provided the total gross mass of the package does not exceed the gross mass for which the design type has been tested; (b) The equipment shall be constructed or packaged in such a manner as to prevent accidental operation during 4 transport; (c) Appropriate measures shall be taken to minimize the effects of vibration and shocks and prevent movement of the equipment within the package that may lead to damage and a dangerous condition during transport. When cushioning material is used to meet this requirement it shall be non-combustible and electrically non-conductive; and (d) The non-combustibility of the cushioning material shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured. (3) The equipment or the batteries may be transported unpackaged under conditions specified by the competent authority. Additional conditions that may be considered in the approval process include, but are not limited to: (a) The equipment or the battery shall be strong enough to withstand the shocks and loadings normally encountered during transport, including transshipment between cargo transport units and between cargo transport units and warehouses as well as any removal from a pallet for subsequent manual or mechanical handling; and (b) The equipment or the battery shall be fixed in cradles or crates or other handling devices in such a way that it will not become loose during normal conditions of transport. Note: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). Additional requirements: The cells and batteries shall be protected against short circuit. Protection against short circuits includes, but is not limited to, (a) individual protection of the battery terminals, (b) inner packaging to prevent contact between cells and batteries, (c) batteries with recessed terminals designed to protect against short circuits, or (d) the use of an electrically non-conductive and non-combustible cushioning material to fill empty space between the cells or batteries in the packaging.

出处：IMDG Code 42-24 第 232 页（4.1.4.1）

P911

P911 本导则适用于 UN3090、3091、3480、3481、3551、3552 下受损或有缺陷的电池和电池组，这些电池和电池组在正常运输条件下可能迅速分解、发生危险反应、产生火焰或危险地放热或危险地释放有毒、腐蚀性或易燃气体或蒸汽。 只要符合第4.1.1和4.1.3条的一般规定，允许使用下列包装： 对于电池和电池组以及含有电池和电池组的设备： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2）。 包装须符合包装类I的性能指标。 （1） 包装须能够满足下述附加性能要求，以防止电池或电池组快速分解、发生危险反应、 产生火焰或危险放热或释放有毒、腐蚀性或易燃气体或蒸汽： （a） 成品包装的外表面温度不得超过100°C。温度瞬间升高至200°C是可以接受的； （b） 包装外部不得出现火焰； （c） 包装中不得有抛射物； （d） 包装的结构的完整性须得到保持； （e） 如适用，包装须配备气体管理系统（例如过滤系统、空气循环、气体容器、气密包装等）。 （2） 附加包装性能要求须经主管当局规定的试验进行验证。* 应要求时须能提供验证报告。作为最低要求，验证报告中须列出电池或电池组的名称、电池或电池组数量、总重、型号、电池或电池组能量容量、包装标识以及按照主管当局规定的验证方法进行的试验数据。 （3） 当使用干冰或液氮作为冷却剂时，须适用第5.5.3节的要求。内包装和外包装须在所使 P911 用的制冷剂温度下以及在失去制冷时可能产生的温度和压力下保持其完整性。 补充规定： 电池或电池组须防止短路。 * 在评估包装的性能时，可考虑以下相关标准： (a) 评估须在一个质量管理系统下进行（如第 2.9.4.5 条所述），以便追溯所使用的试验结果、 参考数据和特性模型； (b) 须明确识别和量化在运输条件下（例如内包装的使用、充电状态（SOC）、使用足够的不易燃、不导电和吸水的衬垫材料等）发生热失控时预期出现的危险清单；电池或电池组可能出现的危险参考清单（例如快速分解、危险反应、产生火焰或危险放热或释放有毒、腐蚀性或易燃气体或蒸汽）可用于此目的。这些危险的量化须依靠现有的科学文献； (c) 须根据所提供保护的性质和建筑材料特性，确定和描述包装的缓解效应。须使用技术特性和图样清单来支持这一评估（密度【kg·m-3】、比热容【J·Kg-1·K-1】、热值 【kJ·Kg-1】、导热系数【W·m-1·K-1】、融化温度和可燃温度【k】、外包装热传导系数【w·m-2·k-1】、…）； (d) 试验和任何支持性计算须评估在正常运输条件下包装内电池或电池组的热失控的结 4 果； (e) 如果电池或电池组的充电状态未知，则须使用与电池或电池组使用条件相对应的最高充电状态进行评估； (f) 须根据包装的气体管理系统描述包装可能使用和运输的环境条件（包括可能对环境造成气体或烟泄排放的影响，如通风或其他方法）； (g) 试验或模型计算须考虑电池或电池组内部热失控触发和传播的最坏情况；这种情况包括正常运输条件下可能出现的最坏故障、反应可能传播的最大热量和火焰排放； (h) 须在足够长的时间内评估这些情况，以允许所有可能的后果发生（例如24小时）； (i) 对于多个电池组和多件包含电池组的设备，须考虑其他要求，例如电池组和设备的最大数量、电池组的最大总能量含量以及包装内的配置，包括部件的分离和保护。

P911 This instruction applies to damaged or defective cells and batteries of UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552 liable to rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours under normal conditions of transport. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: For cells and batteries and equipment containing cells and batteries: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). The packagings shall conform to the packing group I performance level. (1) T he packaging shall be capable of meeting the following additional performance requirements in case of rapid disassembly, dangerous reaction, production of a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours of the cells or batteries: (a) The outside surface temperature of the completed package shall not have a temperature of more than 100°C. A momentary spike in temperature up to 200°C is acceptable; (b) No flame shall occur outside the package; (c) No projectiles shall exit the package; (d) The structural integrity of the package shall be maintained; (e) The packagings shall have a gas management system (e.g. filter system, air circulation, containment for gas, gas tight packaging, etc.), as appropriate. (2) The additional packaging performance requirements shall be verified by a test as specified by the competent authority.* A verification report shall be available on request. As a minimum requirement, the cell or battery name, the cell or battery number, the mass, type, energy content of the cells or batteries, the packaging identification and the test data according to the verification method as specified by the competent authority shall be listed in the verification report. (3) When dry ice or liquid nitrogen is used as a coolant, the requirements of section 5.5.3 shall apply. The inner packaging and outer packaging shall maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost. Additional requirement: Cells or batteries shall be protected against short circuit. * The following criteria, as relevant, may be considered to assess the performance of the packaging: (a) The assessment shall be done under a quality management system (as described, e.g. in section 2.9.4.5) allowing for the traceability of tests results, reference data and characterization models used; △ (b) The list of hazards expected in case of thermal runaway for the cell or battery type, in the condition it is transported (e.g. usage of an inner packaging, state of charge (SOC), use of sufficient non-combustible, electrically non-conductive and absorbent cushioning material, etc.), shall be clearly identified and quantified; the reference list of possible hazards for cells or batteries (e.g. rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours) can be used for this purpose. The quantification of these hazards shall rely on available scientific literature; (c) The mitigating effects of the packaging shall be identified and characterized, based on the nature of the protections provided and the construction material properties. A list of technical characteristics and drawings shall be used to support this assessment (density [kg·m-3], specific heat capacity [J·kg-1·K-1], heating value [kJ·kg-1], thermal conductivity [W·m-1·K-1], melting temperature and flammability temperature [K], heat transfer coefficient of the outer packaging [W·m-2·K-1], …); (d) The test and any supporting calculations shall assess the result of a thermal runaway of the cell or battery inside the packaging in the normal conditions of transport; (e) In case the SOC of the cell or battery is not known, the assessment used shall be done with the highest possible SOC corresponding to the cell or battery use conditions; (f) The surrounding conditions in which the packaging may be used and transported shall be described (including for possible consequences of gas or smoke emissions on the environment, such as ventilation or other methods) according to the gas management system of the packaging; (g) The tests or the model calculation shall consider the worst case scenario for the thermal runaway triggering and propagation inside the cell or battery: this scenario includes the worst possible failure in the normal transport condition, the maximum heat and flame emissions for the possible propagation of the reaction; (h) These scenarios shall be assessed over a period long enough to allow all the possible consequences to occur (e.g. 24 hours). (i) In the case of multiple batteries and multiple items of equipment containing batteries, additional requirements, such as the maximum number of batteries and items of equipment, the total maximum energy content of the batteries, and the configuration inside the package, including separations and protections of the parts, shall be considered.

出处：IMDG Code 42-24 第 233 页（4.1.4.1）

LP903

LP903 条文尚未录入本库，请以 IMDG Code 42-24 原书为准。

LP904

LP904 条文尚未录入本库，请以 IMDG Code 42-24 原书为准。

LP905

LP905 条文尚未录入本库，请以 IMDG Code 42-24 原书为准。

LP906

LP906 条文尚未录入本库，请以 IMDG Code 42-24 原书为准。

SP 188

交付运输的电池和电池组如满足下列条件，不适用本规则的其他规定：.1 对于锂金属或锂合金电池，锂含量不超过1g，对于锂离子或钠离子电池，瓦时额定值不超过20Wh；.2 对于锂金属或锂合金电池，锂含量总计不超过2g，对于锂离子或钠离子电池， 瓦时额定值不超过100瓦时。 符合本规定的锂离子和钠离子电池应在外壳上标明瓦时额定值，2009年1月1日之前生产的锂离子电池除外；.3 每个锂电池或电池组均符合第2.9.4.1、2.9.4.5、2.9.4.6条（如适用）和第 2.9.4.7条的规定，或对于钠离子电池或电池组，须适用第2.9.5.1、2.9.5.5 和 2.9.5.6条的规定；.4 除装在设备中外，电池和电池组须装在完全将其封闭的内包装内。电池或电池组须有防止发生短路的保护措施。这包括防止在同一包装内可能导致短路的与导电材料接触。内包装须装在符合第4.1.1.1、4.1.1.2和4.1.1.5条规定的坚实的外包装内。.5 安装在设备中的电池和电池组须加以保护以避免损坏和短路，该设备须配备有效的防止意外激活的装置。此要求不适用于特意在运输过程中工作且不会产生有危险的热释放的装置(无线电射频识别发射器(RFID)、手表、感应器等)。如果电池组安装于设备内，该设备须被包装在坚实的外包装内，该外包装由具有足够强度的材料制造并且设计与其容量和拟定用途相适应，除非含有这些电池的设备能够提供等效的保护。.6 每个包装件均须标有适当的锂或钠离子电池标记，如图5.2.1.10所示； 注：符合国际民航组织《危险货物航空安全运输技术规则》第4部分第11章包装规范965或968第 IB 节规定包装的装有锂电池的货件，且该货件贴有第 5.2.1.10条所示标志（锂电池标志）和第5.2.2.2.2条关于型号9A 所示标签，即视为符合本特别规定的规定。 此要求不适用于：.1 仅含有安装在设备中的纽扣电池（包括电路板）的包件；以及.2 包装内装有不超过四个电池芯或两个安装在设备中的电池，且一单货物中包件不超过两个。 当包件置于集合包件内时，锂电池或钠电池标记须清晰可见或复制在集合包件外面，集合包件上须标记"OVERPACK"字样。"OVERPACK"标记的高度至少为12mm。.7 除被安装在设备中的电池组外，每个包件须能够承受任何方向1.2m 的跌落试验而内装的电池或电池组不发生损坏，不发生内容物移动造成的电池与电池 (电池组与电池组)相互接触及内容物泄漏；和.8 除电池或电池组安装在设备内或与设备一起包装的情况外，包装件毛重不得超过 30 kg。本特殊规定中的“设备”是指由电池或电池组为其运行提供电力的装置。 如上文和本《规则》其他地方所用，“锂含量”是指锂金属或锂合金电池阳极中锂的质量。 锂金属电池和锂离子电池有单独的条目，以方便这些电池在特定运输方式下的运输，并能够应用不同的应急响应措施。 《测试和标准手册》第 III 部分第 38.3.2.3 小节定义的单电池被视为“电池”，须根据本特殊规定中对“电池”的要求进行运输。

Cells and batteries offered for transport are not subject to other provisions of this Code if they meet the following:.1 For a lithium metal or lithium alloy cell, the lithium content is not more than 1 g, and for a lithium- ion or sodium-ion cell, the watt-hour rating is not more than 20 Wh;.2 For a lithium metal or lithium alloy battery, the aggregate lithium content is not more than 2 g, and for a lithium-ion or sodium-ion battery, the watt-hour rating is not more than 100 Wh. Lithium- ion and sodium-ion batteries subject to this provision shall be marked with the watt-hour rating on the outside case, except lithium-ion batteries manufactured before 1 January 2009;.3 Each lithium cell or battery meets the provisions of 2.9.4.1, 2.9.4.5, 2.9.4.6 if applicable and 2.9.4.7 or for sodium-ion cells or batteries, the provisions of 2.9.5.1, 2.9.5.5 and 2.9.5.6 shall apply;.4 Cells and batteries, except when installed in equipment, shall be packed in inner packagings that completely enclose the cell or battery. Cells and batteries shall be protected so as to prevent short circuits. This includes protection against contact with electrically conductive material within the same packaging that could lead to a short circuit. The inner packagings shall be packed in strong outer packagings which conform to the provisions of 4.1.1.1, 4.1.1.2, and 4.1.1.5;.5 Cells and batteries when installed in equipment shall be protected from damage and short circuit, and the equipment shall be equipped with an effective means of preventing accidental activation.This requirement does not apply to devices which are intentionally active in transport (radio frequency identification (RFID) transmitters, watches, sensors, etc.) and which are not capable of generating a dangerous evolution of heat.When batteries are installed in equipment, the equipment shall be packed in strong outer packagings constructed of suitable material of adequate strength and design in relation to the packaging’s capacity and its intended use unless the battery is afforded equivalent protection by the equipment in which it is contained;.6 Each package shall be marked with the appropriate lithium or sodium ion battery mark, as illustrated in 5.2.1.10; Note: Packages containing lithium batteries packed in conformity with the provisions of part 4, chapter 11, packing instructions 965 or 968, Section IB of the ICAO Technical Instructions for the Safe Transport of Dangerous Goods by Air that bear the mark as shown in 5.2.1.10 (lithium battery mark) and the label shown in 5.2.2.2.2, Model No. 9A shall be deemed to meet the provisions of this special provision. This requirement does not apply to:.1 packages containing only button cell batteries installed in equipment (including circuit boards); and.2 p ackages containing no more than four cells or two batteries installed in equipment, where there are not more than two packages in the consignment. When packages are placed in an overpack, the lithium or sodium battery mark shall either be clearly visible or be reproduced on the outside of the overpack and the overpack shall be marked with the word “OVERPACK”. The lettering of the “OVERPACK” mark shall be at least 12 mm high;.7 Except when cells or batteries are installed in equipment, each package shall be capable of withstanding a 1.2 m drop test in any orientation without damage to cells or batteries contained therein, without shifting of the contents so as to allow battery to battery (or cell to cell) contact and without release of contents; and.8 Except when cells or batteries are installed in or packed with equipment, packages shall not exceed 30 kg gross mass. As used in this special provision “equipment” means apparatus for which the cells or batteries will provide electrical power for its operation. As used above and elsewhere in this Code, “lithium content” means the mass of lithium in the anode of a lithium metal or lithium alloy cell. Separate entries exist for lithium metal batteries and lithium ion batteries to facilitate the transport of these batteries for specific modes of transport and to enable the application of different emergency response actions. A single cell battery as defined in part III, subsection 38.3.2.3 of the Manual of Tests and Criteria is considered a “cell” and shall be transported according to the requirements for “cells” for the purpose of this special provision.

出处：IMDG Code 42-24 第 767 页

SP 230

锂电池及电池组如符合第2.9.4节的规定，可根据本条目运输。钠离子电池及电池组如符合第2.9.5节的规定，可根据本条目运输。

Lithium cells and batteries may be transported under this entry if they meet the provisions of 2.9.4. Sodium-ion cells and batteries may be transported under this entry if they meet the provisions of 2.9.5.

出处：IMDG Code 42-24 第 770 页

SP 310

生产批次不超过 100 个电池或电池组的电池或电池组预生产原型在运输进行测试时，须符合第2.9.4节的规定，但第2.9.4.1、2.9.4.5.7、2.9.4.6.3 （如适用）、2.9.4.6.4（如适用）和 2.9.4.7条除外。 注：“运输进行测试”包括但不限于《测试和标准手册》第 III 部分第 38.3 小节中所述的测试、集成测试和产品性能测试。 这些电池和电池组须根据第4.1.4.1条的包装导则P910 或第4.1.4.3条的 LP905（如适用）进行包装。 物品（UN 3537、3538、3540、3541、3546、3547 或 3548）可包含此类电池或电池组，但须符合第4.1.4.1条包装导则P006 或第4.1.4.3条LP03 的适用部分。 运输单证须包括以下声明：“按照特殊规定 310 运输”。 受损或有缺陷的电池、电池组或设备中所含的电池和电池组须按照特殊规定 376 运输。 运输用于处置或回收的电池、电池或设备中所含的电池和电池组可按照特殊规定 377 和第4.1.4.1条包装导则P909 进行包装。

Cells or batteries from production runs of not more than 100 cells or batteries, or pre-production prototypes of cells or batteries when these prototypes are transported for testing, shall meet the provisions of 2.9.4 with the exception of 2.9.4.1, 2.9.4.5.7, 2.9.4.6.3 if applicable, 2.9.4.6.4 if applicable and 2.9.4.7. Note: “Transported for testing” includes, but is not limited to, testing described in the Manual of Tests and Criteria, part III, subsection 38.3, integration testing and product performance testing. These cells and batteries shall be packaged in accordance with packing instruction P910 of 4.1.4.1 or LP905 of 4.1.4.3, as applicable. Articles (UN Nos. 3537, 3538, 3540, 3541, 3546, 3547 or 3548) may contain such cells or batteries provided that the applicable parts of packing instruction P006 of 4.1.4.1 or LP03 of 4.1.4.3, as applicable, are met. The transport document shall include the following statement: “Transport in accordance with special provision 310”. Damaged or defective cells, batteries, or cells and batteries contained in equipment shall be transported in accordance with special provision 376. Cells, batteries or cells and batteries contained in equipment transported for disposal or recycling may be packaged in accordance with special provision 377 and packing instruction P909 of 4.1.4.1.

出处：IMDG Code 42-24 第 776 页

SP 376

被确定为损坏或有缺陷的锂金属、锂离子或钠离子电池或电池组，如果它们不符合《测试和标准手册》适用条款所规定的测试类型，则须符合本特殊规定的要求。 就本特殊规定而言，这些可能包括但不限于： – 因安全原因被确定为有缺陷的电池或电池组； – 电池或电池组泄漏或漏气； – 运输前无法诊断的电池或电池组；或 – 电池或电池组遭受物理或机械损坏。 注：在评估电池或电池组是否损坏或有缺陷时，须根据电池、电池组或产品制造商的安全标准或由了解电池或电池组安全特性的技术专家进行评估或鉴定。评估或鉴定可包括但不限于以下标准：.1 急性危险，例如气体、火灾或电解质泄漏；.2 电池或电池组的使用或误用；.3 物理损坏迹象，例如电池或电池组外壳变形或外壳颜色；.4 外部和内部短路保护，例如电压或隔离措施；.5 电池或电池组安全功能的状况；或.6 任何内部安全部件损坏，例如电池管理系统。 电池和电池组须根据适用于 UN 3090、UN 3091、UN 3480、UN 3481、 UN 3551 和 UN 3552 的规定进行运输，但特殊规定 230 和本特殊规定另有规定除外。 电池和电池组须根据第4.1.4.1条的包装导则P908或第4.1.4.3条的LP904 进行包装。 在正常运输条件下，被确定为损坏或有缺陷且易于快速分解、发生危险反应、产生火焰或危险放热或危险释放有毒、腐蚀性或易燃气体或蒸汽的电池和电池组须根据第4.1.4.1条的包装导则P911 或第4.1.4.3条的LP906 进行包装和运输。主管当局可批准替代包装和/或运输条件。 除正确运输名称外，包装还须标明“损坏/缺陷”，如第5.2.1节所述。 运输单证须包括以下声明“按照特殊规定 376 运输”。 如适用，运输时须附上主管部门批准的副本。

Lithium metal, lithium ion or sodium ion cells or batteries identified as being damaged or defective such that they do not conform to the type tested according to the applicable provisions of the Manual of Tests and Criteria shall comply with the requirements of this special provision. For the purposes of this special provision, these may include, but are not limited to: – Cells or batteries identified as being defective for safety reasons; – Cells or batteries that have leaked or vented; – Cells or batteries that cannot be diagnosed prior to transport; or – Cells or batteries that have sustained physical or mechanical damage. Note: In assessing a cell or battery as damaged or defective, an assessment or evaluation shall be performed based on safety criteria from the cell, battery or product manufacturer or by a technical expert with knowledge of the cell’s or battery’s safety features. An assessment or evaluation may include, but is not limited to, the following criteria:.1 acute hazard, such as gas, fire or electrolyte leaking;.2 the use or misuse of the cell or battery;.3 signs of physical damage, such as deformation to cell or battery casing, or colours on the casing;.4 external and internal short circuit protection, such as voltage or isolation measures;.5 the condition of the cell or battery safety features; or.6 damage to any internal safety components, such as the battery management system. Cells and batteries shall be transported according to the provisions applicable to UN 3090, UN 3091, UN 3480, UN 3481, UN 3551 and UN 3552, as appropriate, except special provision 230 and as otherwise stated in this special provision. Cells and batteries shall be packed in accordance with packing instructions P908 of 4.1.4.1 or LP904 of 4.1.4.3, as applicable. Cells and batteries identified as damaged or defective and liable to rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours under normal conditions of transport shall be packed and transported in accordance with packing instruction P911 of 4.1.4.1 or LP906 of 4.1.4.3, as applicable. Alternative packing and/or transport conditions may be authorized by the competent authority. Packages shall be marked “DAMAGED/DEFECTIVE” in addition to the proper shipping name, as stated in 5.2.1. The transport document shall include the following statement “Transport in accordance with special provision 376”. If applicable, a copy of the competent authority approval shall accompany the transport.

出处：IMDG Code 42-24 第 785 页

SP 377

锂金属、锂离子和钠离子电池和电池组以及装有此类电池和电池组的设备，无论是否与非锂或非钠离子电池一起包装或单独包装，均可按照第 4.1.4.1条的包装导则P909 进行包装。 这些电池和电池组不受第2.9.4 或 2.9.5节要求的约束。 包装件须标明“待处置的锂电池”、“待处置的钠离子电池”、“待回收的锂电池”或“待回收的钠离子电池”，视情而定。 经识别的损坏或有缺陷的电池须按照特殊规定 376 进行运输。 运输单证须包括以下声明：“按照特殊规定 377 进行运输”

Lithium metal, lithium ion and sodium ion cells and batteries and equipment containing such cells and batteries transported for disposal or recycling, either packed together with or packed without non-lithium or non-sodium ion batteries, may be packaged in accordance with packing instruction P909 of 4.1.4.1. These cells and batteries are not subject to the requirements of section 2.9.4 or 2.9.5. Packages shall be marked “LITHIUM BATTERIES FOR DISPOSAL”, “SODIUM ION BATTERIES FOR DISPOSAL”, “LITHIUM BATTERIES FOR RECYCLING”, or “SODIUM ION BATTERIES FOR RECYCLING”, as appropriate. Identified damaged or defective batteries shall be transported in accordance with special provision 376. The transport document shall include the following statement: “Transport in accordance with special provision 377”.

出处：IMDG Code 42-24 第 785 页

SP 384

使用的标签为图例 No 9A，见第5.2.2.2.2条。但对于货物运输组件的标牌，标牌与图例 No 9A相对应。

The label to be used is Model No. 9A, see 5.2.2.2.2. However, for placarding of cargo transport units, the placard shall correspond to Model No. 9.

出处：IMDG Code 42-24 第 786 页

SP 387

符合第2.9.4.6条的锂电池包含一次锂金属电池和可充电锂离子电池，须酌情归入 UN 3090 或 3091。当此类电池按照特殊规定188 运输时，电池中所有锂金属电池的总锂含量不得超过1.5 g，电池中所有锂离子电池的总容量不得超过10 Wh。

Lithium batteries in conformity with 2.9.4.6 containing both primary lithium metal cells and rechargeable lithium ion cells shall be assigned to UN 3090 or 3091 as appropriate. When such batteries are transported in accordance with special provision 188, the total lithium content of all lithium metal cells contained in the battery shall not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery shall not exceed 10 Wh.

出处：IMDG Code 42-24 第 787 页

除非是短程的国际运输，按照特殊规定376或377运输的电池组为积载类C。

For batteries transported in accordance with special provisions 376 or 377, category C, unless transported on a short international voyage.