IMDG Code 42-24 · Dangerous Goods List

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UN2014HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary)

English proper shipping name · Check the cargo and applicable provisions before shipment.

Class5.1
Packing groupII
EmSF-H, S-Q

Dangerous Goods List entries

The comparison below lists all entries. Expanded provisions and the label preview on this page apply to Entry 1.

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Entry 1 · Packing group II

HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary)

Class
5.1
Subsidiary risk / reference
8
Packing group
II
Marine pollutant entry
Not listed; check the cargo classification
Limited quantities
1 L
Excepted quantities
E2
Packing instruction
P504
Special provisions
Not listed
Special packing provision
PP10
IBC instruction
IBC02
IBC special provisions
B5
Portable tank / bulk container codes
T7
Tank special provisions
TP2 TP6 TP24
EmS
F-H, S-Q
Stowage and handling
Category D SW1 Category D SW1
Segregation
SGG16 SG16 SG59 SG72
Properties and observations · source text
Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. In contact with combustible material, may cause fire or explosion. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen.

Packing and large packaging instructions

P504

Source pages and references

Check original English pages and footnotes ↗ · official PDF 210–210

P504 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met. Combination packagings Maximum net mass (1) Outer packagings: (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 75 kg 4C2, 4D, 4F, 4G, 4H2) Inner packagings: Glass receptacles with a maximum capacity of 5 L (2) Outer packagings: (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 75 kg 4C2, 4D, 4F, 4G, 4H2) Inner packagings: Plastics receptacles with a maximum capacity of 30 L (3) Outer packagings: (1G, 4F or 4G) 125 kg Inner packagings: Metal receptacles with a maximum capacity of 40 L (4) Outer packagings: (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 4A, 4B, 4N, 4C1, 4C2, 4D, 225 kg 4H2) Inner packagings: Metal receptacles with a maximum capacity of 40 L Single packagings Maximum capacity Drums steel, non-removable head (1A1) 250 L aluminium, non-removable head (1B1) 250 L metal, other than steel or aluminium, non-removable head (1N1) 250 L plastics, non-removable head (1H1) 250 L Jerricans steel, non-removable head (3A1) 60 L aluminium, non-removable head (3B1) 60 L plastics, non-removable head (3H1) 60 L Composite packagings Plastics receptacle in steel or aluminium drum (6HA1, 6HB1) 250 L Plastics receptacle in fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) 120 L Plastics receptacle in steel or aluminium crate or box or plastics receptacle in wood, 60 L plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) Glass receptacle in steel, aluminium, fibre or plywood drum (6PA1, 6PB1, 6PD1 or 6PG1) 60 L or in a steel, aluminium, wood or fibreboard box or in wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) or in expanded or solid plastics packaging (6PH1 or 6PH2) Special packing provisions: PP10 For UN Nos. 2014 and 3149, the packaging shall be vented. PP31 For UN 2626, packagings shall be hermetically sealed.

IMDG Code 42-24 · English source text

Special packing provisions

IBC instructions

IBC02

Source pages and references

Check original English pages and footnotes ↗ · official PDF 231–231

IBC02 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Special packing provisions: B5 For UN Nos. 1791, 2014, 2984 and 3149, IBCs shall be provided with a device to allow venting during transport. The inlet to the venting device shall be sited in the vapour space of the IBC under maximum filling conditions during transport. B8 The pure form of this substance shall not be transported in IBCs since it is known to have a vapour pressure of more than 110 kPa at 50C or 130 kPa at 55C. ° ° B15 For UN 2031 with more than 55% nitric acid, the permitted use of rigid plastics IBCs and of rigid plastics inner receptacles of composite IBCs shall be two years from their date of manufacture. B16 For UN 3375, IBCs of type 31A and 31N are not allowed without competent authority approval. B20 For UN Nos. 1716, 1717, 1736, 1737, 1738, 1742, 1743, 1755, 1764, 1768, 1776, 1778, 1782, 1789, 1790, 1796, 1826, 1830, 1832, 2031, 2308, 2353, 2513, 2584, 2796 and 2817 coming under PG II, IBCs shall be fitted with two shut-off devices.

IMDG Code 42-24 · English source text

IBC special provisions

B5

Applies under IBC02

Source pages and references

Check original English pages and footnotes ↗ · official PDF 231–231

For UN Nos. 1791, 2014, 2984 and 3149, IBCs shall be provided with a device to allow venting during transport. The inlet to the venting device shall be sited in the vapour space of the IBC under maximum filling conditions during transport.

IMDG Code 42-24 · English source text

Portable tank instructions

T7

Source pages and references

Check original English pages and footnotes ↗ · official PDF 260–267

These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells.

T7 · Selected instruction · IMDG 42-24
Portable tank instructionMinimum test pressure (bar)Minimum shell thickness (in mm – reference steel) (see 6.7.2.4)Pressure relief provisionsa (see 6.7.2.8)Bottom opening provisionsb (see 6.7.2.6)
T74See 6.7.2.4.2NormalSee 6.7.2.6.3

a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

Source PDF pages:264 · 42-24

Extracted source text
S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 4 See 6.7.2.4.2 Normal See 6.7.2.6.3

IMDG Code 42-24 · English source text

Tank special provisions

TP6

Source pages and references

Check original English pages and footnotes ↗ · official PDF 268–268

To prevent the tank bursting in any event, including fire engulfment, it shall be provided with pressure- relief devices which are adequate in relation to the capacity of the tank and to the nature of the substance transported. The device shall also be compatible with the substance.

IMDG Code 42-24 · English source text

TP24

Source pages and references

Check original English pages and footnotes ↗ · official PDF 268–268

The portable tank may be fitted with a device located, under maximum filling conditions, in the vapour space of the shell to prevent the build-up of excess pressure due to the slow decom position of the substance transported. This device shall also prevent an unacceptable amount of leakage of liquid in the case of overturning or entry of foreign matter into the tank. This device shall be approved by the competent authority or its authorized body.

IMDG Code 42-24 · English source text

Stowage and handling codes

Segregation groups

Segregation codes

Labels and marks

Reference preview for Entry 1 · Packing group II. Confirm the cargo classification and any conditions in the special provisions.

Oxidizer 5.1
Oxidizer 5.1
Corrosive 8
Corrosive 8

This UN may be carried as a limited quantity (Code allocation 1 L); if this consignment is shipped as LQ, the LQ mark must be applied and chapter 3.4 complied with

This UN may be carried as an excepted quantity (code E2); if this consignment is shipped as EQ, the EQ mark must be applied and chapter 3.5 complied with

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