IMDG Code 42-24 · Dangerous Goods List

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UN3152POLYHALOGENATED BIPHENYLS, SOLID or HALOGENATED MONOMETHYL- DIPHENYLMETHANES, SOLID or POLYHALOGENATED TERPHENYLS, SOLID

English proper shipping name · Check the cargo and applicable provisions before shipment.

Class9
Packing groupII
EmSF-A, S-A

Dangerous Goods List entries

The comparison below lists all entries. Expanded provisions and the label preview on this page apply to Entry 1.

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Entry 1 · Packing group II

POLYHALOGENATED BIPHENYLS, SOLID or HALOGENATED MONOMETHYL- DIPHENYLMETHANES, SOLID or POLYHALOGENATED TERPHENYLS, SOLID

Class
9
Subsidiary risk / reference
Not listed
Packing group
II
Marine pollutant entry
P
Limited quantities
1 kg
Excepted quantities
E2
Packing instruction
P906
Special provisions
203 305 958
Special packing provision
Not listed
IBC instruction
IBC08
IBC special provisions
B4 B21
Portable tank / bulk container codes
T3
Tank special provisions
TP33
EmS
F-A, S-A
Stowage and handling
Category A Category A
Segregation
SG50
Properties and observations · source text
Solid with a perceptible odour. Melting point of solids varies from 2 C to 164 C. Harmful by ingestion or by skin contact. This entry also ° ° covers articles, such as rags, cotton waste, clothing or sawdust, containing polyhalogenated biphenyls or polyhalogenated terphenyls where no free visible liquid is present.

Packing and large packaging instructions

P906

Source pages and references

Check original English pages and footnotes ↗ · official PDF 225–225

P906 This instruction applies to UN Nos. 2315, 3151, 3152 and 3432. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: (1) For liquids and solids containing or contaminated with PCBs, polyhalogenated biphenyls, polyhalogenated terphenyls or halogenated monomethyldiphenylmethanes: Packagings in accordance with P001 or P002, as appropriate. (2) For transformers and condensers and other articles: (a) Packagings in accordance with packing instructions P001 or P002. The articles shall be secured with suitable cushioning material to prevent inadvertent movement during normal conditions of transport; or (b) Leakproof packagings which are capable of containing, in addition to the articles, at least 1.25 times the volume of the liquid PCBs, polyhalogenated biphenyls, polyhalogenated terphenyls or halogenated monomethyldiphenylmethanes present in them. There shall be sufficient absorbent material in the packagings to absorb at least 1.1 times the volume of liquid which is contained in the articles. In general, transformers and condensers shall be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and condensers, at least 1.25 times the volume of the liquid present in them. Note 1: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). Notwithstanding the above, liquids and solids not packaged in accordance with P001 and P002 and unpackaged transformers and condensers may be transported in cargo transport units fitted with a leakproof metal tray to a height of at least 800 mm, containing sufficient inert absorbent material to absorb at least 1.1 times the volume of any free liquid. Note 2: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). Additional provision: Adequate provisions shall be taken to seal the transformers and condensers to prevent leakage during normal conditions of transport.

IMDG Code 42-24 · English source text

IBC instructions

IBC08

Source pages and references

Check original English pages and footnotes ↗ · official PDF 232–232

IBC08 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fibreboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Additional provisions: Where the solid may become liquid during transport see 4.1.3.4. Special packing provisions: B3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B4 Flexible, fibreboard or wooden IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B6 For UN Nos. 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC testing provisions of chapter 6.5. B21 For solid substances in IBCs other than metal or rigid plastics IBCs, the IBCs shall be carried in closed cargo transport units or in freight containers/vehicles, which shall have rigid sides or fences at least to the height of the IBC.

IMDG Code 42-24 · English source text

IBC special provisions

B4

Applies under IBC08

Source pages and references

Check original English pages and footnotes ↗ · official PDF 232–232

Flexible, fibreboard or wooden IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

IMDG Code 42-24 · English source text

B21

Applies under IBC08

Source pages and references

Check original English pages and footnotes ↗ · official PDF 232–232

For solid substances in IBCs other than metal or rigid plastics IBCs, the IBCs shall be carried in closed cargo transport units or in freight containers/vehicles, which shall have rigid sides or fences at least to the height of the IBC.

IMDG Code 42-24 · English source text

Portable tank instructions

T3

Source pages and references

Check original English pages and footnotes ↗ · official PDF 260–267

These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells.

T3 · Selected instruction · IMDG 42-24
Portable tank instructionMinimum test pressure (bar)Minimum shell thickness (in mm – reference steel) (see 6.7.2.4)Pressure relief provisionsa (see 6.7.2.8)Bottom opening provisionsb (see 6.7.2.6)
T32.65See 6.7.2.4.2NormalSee 6.7.2.6.2

a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

Source PDF pages:264 · 42-24

Extracted source text
S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 2.65 See 6.7.2.4.2 Normal See 6.7.2.6.2

IMDG Code 42-24 · English source text

Tank special provisions

TP33

Source pages and references

Check original English pages and footnotes ↗ · official PDF 267–269

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19.

IMDG Code 42-24 · English source text

Special provisions

SP 305

Source pages and references

Check original English pages and footnotes ↗ · official PDF 763–763

These substances are not subject to the provisions of this Code when in concentrations of not more than 50 mg/kg.

IMDG Code 42-24 · English source text

SP 958

Source pages and references

Check original English pages and footnotes ↗ · official PDF 782–782

This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polychlorinated biphenyls, polyhalogenated biphenyls or polyhalogenated terphenyls where no free visible liquid is present.

IMDG Code 42-24 · English source text

Segregation codes

Labels and marks

Reference preview for Entry 1 · Packing group II. Confirm the cargo classification and any conditions in the special provisions.

Miscellaneous 9
Miscellaneous 9
Marine pollutant mark
Marine pollutant mark

This UN may be carried as a limited quantity (Code allocation 1 kg); if this consignment is shipped as LQ, the LQ mark must be applied and chapter 3.4 complied with

This UN may be carried as an excepted quantity (code E2); if this consignment is shipped as EQ, the EQ mark must be applied and chapter 3.5 complied with

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