BATTERIES, CONTAINING METALLIC SODIUM OR SODIUM ALLOY or CELLS, CONTAINING METALLIC SODIUM OR SODIUM ALLOY
Class
4.3
Subsidiary risk / reference
Not listed
Packing group
Not assigned in this entry
Marine pollutant entry
Not listed; check the cargo classification
Limited quantities
0
Excepted quantities
E0
Packing instruction
P408
Special provisions
239 401
Special packing provision
Not listed
IBC instruction
Not listed
IBC special provisions
Not listed
Portable tank / bulk container codes
Not listed
Tank special provisions
Not listed
EmS
F-G, S-P
Stowage and handling
Category A H1 Category A H1
Segregation
SG26
Properties and observations · source text
Series of hermetically sealed metal cells containing sodium, electrically connected and secured within a metal casing. “Cold” batteries (batteries containing elemental sodium only in the solid state) are electrically inert. Batteries are activated by heating to between 300 C and 350 C before operating to produce electricity. ° ° Activated batteries (i.e. “hot” batteries containing liquid elemental sodium) may cause fire through short-circuit of the terminals. Batteries or cells should not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell unless approved, and under conditions of transport established by the competent authority.
P408 This instruction applies to UN 3292. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) For cells: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). There shall be sufficient cushioning material to prevent contact between cells and between cells and the internal surfaces of the outer packaging and to ensure that no dangerous movement of the cells within the outer packaging occurs in transport. Packagings shall conform to the packing group II performance level. (2) Batteries may be transported unpacked or in protective enclosures (e.g. fully enclosed or wooden slatted crates). The terminals shall not support the weight of other batteries or materials packed with the batteries. Packagings need not meet the requirements of 4.1.1.3. Note: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). Additional requirement: Cells and batteries shall be protected against short circuit and shall be isolated in such a manner as to prevent short circuits.
Batteries or cells shall not contain dangerous goods other than sodium, sulphur or sodium compounds (e.g. sodium polysulphides and sodium tetrachloroaluminate). Batteries or cells shall not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell, unless approved and under the conditions established by the competent authority. Cells shall consist of hermetically sealed metal casings which fully enclose the dangerous goods and which are so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport. Batteries shall consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport.
Sodium ion cells and batteries with organic electrolyte shall be transported as UN 3551 or 3552, as appropriate. Sodium ion cells and batteries with aqueous alkali electrolyte shall be transported as UN 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage.
In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.
IMDG Code 42-24 · English source text
Labels and marks
Reference preview for Entry 1. Confirm the cargo classification and any conditions in the special provisions.