UN3396ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE

P410 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met. Combination packagings Maximum net mass Glass 10 kg Drums Plastics1 30 kg steel (1A1, 1A2) 400 kg 400 kg Metal 40 kg aluminium (1B1, 1B2) 400 kg 400 kg Paper1, 2 10 kg other metal (1N1, 1N2) 400 kg 400 kg plastics (1H1, 1H2) 400 kg 400 kg Fibre1, 2 10 kg plywood (1D) 400 kg 400 kg fibre (1G)1 kg 400 kg Boxes steel (4A) 400 kg 400 kg aluminium (4B) 400 kg 400 kg other metal (4N) 400 kg 400 kg natural wood (4C1) 400 kg 400 kg natural wood with sift-proof 400 kg 400 kg walls (4C2) plywood (4D) kg 400 kg reconstituted wood (4F) kg 400 kg fibreboard (4G)1 kg 400 kg expanded plastics (4H1) kg 60 kg solid plastics (4H2) kg 400 kg Jerricans Packagings shall be sift-proof. steel (3A1, 3A2) 120 kg 120 kg These inner packagings shall not be used aluminium (3B1, 3B2) 120 kg 120 kg when the substances being transported plastics (3H1, 3H2) 120 kg 120 kg may become liquid during transport (see 4.1.3.4). Single packagings Drums steel (1A1 or 1A2) 400 kg 400 kg aluminium (1B1 or 1B2) 400 kg 400 kg metal other than steel or aluminium (1N1 or 1N2) 400 kg 400 kg 4 plastics (1H1 or 1H2) 400 kg 400 kg Jerricans steel (3A1 or 3A2) 120 kg 120 kg aluminium (3B1 or 3B2) 120 kg 120 kg plastics (3H1 or 3H2) 120 kg 120 kg Boxes steel (4A)3 400 kg 400 kg aluminium (4B)3 400 kg 400 kg other metal (4N)3 400 kg 400 kg natural wood (4C1)3 400 kg 400 kg natural wood with sift-proof walls (4C2)3 400 kg 400 kg plywood (4D)3 kg 400 kg reconstituted wood (4F)3 kg 400 kg fibreboard (4G)3 kg 400 kg solid plastics (4H2)3 kg 400 kg Bags Bags (5H3, 5H4, 5L3, 5M2)3, 4 50 kg 50 kg Composite packagings Plastics receptacle in steel, aluminium, plywood, fibre or plastics drum 400 kg 400 kg (6HA1, 6HB1, 6HG1, 6HD1 or 6HH1) Plastics receptacle in steel or aluminium crate or box, wooden box, 75 kg 75 kg plywood box, fibreboard box or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) Glass receptacle in steel, aluminium, plywood or fibre drum 75 kg 75 kg (6PA1, 6PB1, 6PD1 or 6PG1) or in steel, aluminium, wooden, wickerwork hamper or fibreboard box (6PA2, 6PB2, 6PC, 6PD2 or 6PG2) or in expanded or solid plastics packaging (6PH1 or 6PH2) These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4). For packing group II substances, these packagings may only be used when transported in a closed cargo transport unit. Pressure receptacles, provided that the general provisions of 4.1.3.6 are met (continued) P410 Special packing provisions: PP31 For UN Nos. 1326, 1339, 1340, 1341, 1343, 1352, 1358, 1373, 1374, 1378, 1379, 1382, 1384, 1385, 1390, 1393, 1394, 1395, 1396, 1398, 1400, 1401, 1402, 1405, 1409, 1417, 1418, 1431, 1436, 1437, 1871, 1923, 1929, 2004, 2008, 2318, 2545, 2546, 2624, 2805, 2813, 2830, 2835, 2844, 2881, 2940, 3078, 3088, 3131, 3132, 3134, 3135, 3170, 3182, 3189, 3190, 3205, 3206, 3208, 3209, 3395, 3396 and 3397, packagings shall be hermetically sealed. PP39 For UN 1378, for metal packagings a venting device is required. PP40 For the following UN Nos., falling in PG II, bags are not allowed: 1326, 1340, 1352, 1358, 1374, 1378, 1382, 1390, 1393, 1394, 1395, 1396, 1400, 1401, 1402, 1405, 1409, 1417, 1418, 1436, 1437, 1871, 2624, 2805, 2813, 2830, 2835, 3078, 3131, 3132, 3134, 3170, 3182, 3208 and 3209. PP83 Deleted PP100 For UN 2950 flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

For UN Nos. 1326, 1339, 1340, 1341, 1343, 1352, 1358, 1373, 1374, 1378, 1379, 1382, 1384, 1385, 1390, 1393, 1394, 1395, 1396, 1398, 1400, 1401, 1402, 1405, 1409, 1417, 1418, 1431, 1436, 1437, 1871, 1923, 1929, 2004, 2008, 2318, 2545, 2546, 2624, 2805, 2813, 2830, 2835, 2844, 2881, 2940, 3078, 3088, 3131, 3132, 3134, 3135, 3170, 3182, 3189, 3190, 3205, 3206, 3208, 3209, 3395, 3396 and 3397, packagings shall be hermetically sealed.

IBC06 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1). Additional provision: Where the solid may become liquid during transport see 4.1.3.4. Special packing provisions: B1 For packing group I substances, IBCs shall be carried in closed cargo transport units or in freight containers/ vehicles, which shall have rigid sides or fences at least to the height of the IBC. B12 For UN 2907, IBCs shall meet the packing group II performance level. IBCs meeting the test criteria of packing group I shall not be used. B21 For solid substances in IBCs other than metal or rigid plastics IBCs, the IBCs shall be carried in closed cargo transport units or in freight containers/vehicles, which shall have rigid sides or fences at least to the height of the IBC.

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19.

Fusible elements in the vapour space may be used on portable tanks.

T he 2.5-year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. However, this examination is required when the conditions of 6.7.2.19.7 are met.

If the chemical or physical properties of a substance covered by this description are such that, when tested, it does not meet the established defining criteria for the class or division listed in column 3, or any other class or division, it is not subject to the provisions of this Code except in the case of a marine pollutant where 2.10.3 applies.

For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8.1). For UN 3077 and UN 3082 only, the technical name may be a name shown in capital letters in column 2 of the Dangerous Goods List, provided that this name does not include “N.O.S.” and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).

Clear of living quarters.

Keep as dry as reasonably practicable.

In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

Stow “separated from” SGG1 – acids.

See tables in 7.2.6.3.